They are currently listed under Per-site methods → Users; they should be listed under Network Methods → Users instead, just like
The sub-header clearly states the difference between:
Each of these methods operates on a single site at a time, identified by the site parameter. This parameter can be the full domain name (ie. "stackoverflow.com"), or a short form identified by api_site_parameter on the site object.
These methods return data across the entire Stack Exchange network of sites. Accordingly, you do not pass a site parameter to them.